I'll try to clarify:
Picking from the screen is one way to make a selection. Selection can also be done with menu or command.
<http://www.cgl.ucsf.edu/chimera/docs/UsersGuide/selection.html>
So, you could either select two atoms (using picking or menu or command) and then click the Create button, as in method 1 above, or use method 2 picking with doubleclicking the second atom as you pick it instead of using the Create button