I have a Windows 8 pro machine, 64-bit 8 GB RAM Core i3 and Quadro FX 570.
When I start Chimera (x86 and x86-64), I see the splash screen then it says "pythonw.exe has stopped working". When I add --debug:
Cannot execute 'gzip': no automatic decompression of .Z files
initializing general preferences
loading Tix
initializing graphics
I managed to cause windows to try to send an error report, which captured these files:
C:\Users\dek\AppData\Local\Temp\WERF405.tmp.appcompat.txt
C:\Users\dek\AppData\Local\Temp\WERF464.tmp.mdmp
if those are useful for debugging, I can provide them.