The bfactor is assigned to every atom. But pLDDT is only assigned for each residue and measures CA position so you might want to look at only the CA lines.
$ grep CA ~/Downloads/ChimeraX/AlphaFold/prediction_14/af252_unrelaxed_rank_1_model_2.pdb
ATOM 2 CA ASP B 1 0.545 -35.783 -13.373 1.00 85.53 C
ATOM 10 CA CYS B 2 1.983 -32.130 -13.721 1.00 95.45 C
ATOM 16 CA PRO B 3 3.029 -30.770 -17.151 1.00 93.20 C
ATOM 23 CA SER B 4 6.629 -31.094 -18.066 1.00 93.36 C
You can also write the values into a ChimeraX attribute file using ChimeraX commands
select #1@CA
save ~/Desktop/plddt.defattr attrName bfactor models #1 selectedOnly true
and that file looks like the following
attribute: bfactor
recipient: atoms
match mode: 1-to-1
/A:1@CA 56.150001525878906
/A:2@CA 53.33000183105469
/A:3@CA 53.59000015258789
/A:4@CA 59.380001068115234
documentation here